Treatment of tannery wastewater by electrocoagulation

Treatment of tannery wastewater by electrocoagulation with low cell current(≤1A)and soluble electrodes(mild steel electrodes and aluminum electrodes)was studied.Compared with aluminum electrodes,mild steel electrodes were more effective for the removal of sulfide,with a removal efficiency of over 90%.But during the treatment process,black color precipitate typical to iron(Ⅱ)sulfides was produced.While aluminum electrodes were effective to eliminate the colority of the effluent,the removal efficiency of sulfide was lower than 12%.The mechanisms of the removal of chemical oxygen demand,ammonia,total organic carbon,sulfide and colority with the two soluble electrodes(mild steel and aluminum electrodes)were discussed in detail.In order to exert the predominance of diffenent types of electrodes,the tannery wastewater was treated using mild steel electrodes first followed by the filter and finally by the aluminum electrodes,the elimination rates of chemical oxygen demand,ammonia,total organic carbon,sulfide and colority were 68.0%,43.1%,55.1%,96.7% and 84.3%,respectively,with the initial concentrations 2413.1 mg/L,223.4 mg/L,1000.4 mg/L,112.3 mg/L and 256 dilution times,respectively.The absorbance spectra and energy consumption during electrocoagulation process were also discussed.     

云南省昆明市生态绿地建造探讨

简介了生态城市绿地建设发展现状，分析了昆明市生态绿地建设进展情况，提出了基于环境功能昆明生态绿地建设的建议：优化生态结构，多生态单元为本底的生态系统，城乡生态系统的连通，城市生态的水网化和林网化，入湖河道下游自然化。     

Improving the environmental performance of machine-tools: influence of technology and throughput on the electrical energy consumption of a press-brake

Machine-tools have been identified as one of the main energy-using products to be analyzed in an Ecodesign perspective, targeting the reduction of their environmental impact. Following this, machine-tool manufacturers are committed to anticipate eminent regulations and are looking for guidelines to improve their products on an effective and low-cost manner. This paper describes part of the energy consumption study followed in the frame of the Ecodesign of a commercial press-brake. All-hydraulic and all-electric commercially available systems, of different capacities and working in real production scenarios, have been included. From this study, a preliminary version of an LCI dataset for the bending process is proposed, structured in technology, machine capacity and usage mode categories, and using the bending cycle as the reference unit. The energy consumption per category was estimated based on a specific process energy model built as a function of the referred parameters. The contribution of the respective machine-tool structure to the environmental impact of the machining process is to be included, targeting the completion of such machining unit process dataset. The full LCA of an all-hydraulic system revealed the significant contribution of the machine-tool structure to the global life-cycle environmental impact of the machine (about 40%), while electricity during use phase contributes with about 46% to the total impact. This contradicts the general results published for other metal and non-metal forming processes, and is understood to be related with the discrete loading character of such forming processes here discussed.     

二氧化锰氧化降解五氯酚

以二氧化锰为氧化剂,研究了pH 4.12的水溶液中五氯酚氧化降解的反应动力学,并讨论了反应溶液的pH对反应动力学的影响.结果表明,五氯酚对二氧化锰的氧化作用具有较强的反应感受性.在pH一定和二氧化锰充分过量的条件下,随着反应的进行,五氯酚的降解速度变慢,遵循的不是简单的准一级反应动力学而是复合的反应动力学.此外,随溶液pH由3.5升高6.6,五氯酚的降解速度发生显著地下降.运用溶剂萃取和气质联用仪的分析方法,检测到2个主产物和1个次产物.其中,次产物是由四氯-1,4-氢醌与四氯儿茶酚组成的混合物;2个主产物是由五氯酚氧自由基偶合而成的二聚体,且是同分异构体.在观测到的表面反应动力学和降解产物的基础上,提出了五氯酚被二氧化锰氧化降解的反应流程图.     

中等城市居民生活消费生态系统占用的比较分析——以泰州、商丘、铜川、锡林郭勒为例

论文引入生态足迹用于分析城市居民消费,通过选取代表不同经济水平和具有不同消费特点的泰州、商丘、铜川、锡林郭勒4个地级市(盟),从生态系统占用角度计算并分析了不同地区中等城市居民生活消费生态系统占用的差异。结果表明:泰州、商丘、铜川90%左右的生态占用来自人们对吃穿的消费,而锡林郭勒这部分的占用则不到70%,其相当一部分占用是来自为了克服较差的气候条件而产生的取暖用煤量;位于草原地区的锡林郭勒多消费牛羊肉,对草地的人均占用多达0.333hm2,是其他地区的数倍,位于长江流域的泰州水产消费较其他地区多,对水域的人均占用达到了0.116hm2,另外三地仅及其16%～45%。结合4城市的生态空间分析发现,仅商丘、泰州、铜川的城镇居民生活消费所占用的生态空间就已经超出了整个城市地区的生态承载水平,即使是地广人稀的锡林郭勒,城镇居民生活消费的生态占用也已接近全盟生态承载的1/2。显然,城市是一类典型的生态赤字区,如何有效调节城市居民的消费方式与消费结构,对于促进城市的可持续发展具有十分重要的意义。     

水源中央空调环境影响的生命周期评价

从原材料获取、生产加工、运行使用和废弃后处理处置 4个阶段 ,对水源中央空调按污染排放和资源能源消耗2种类型进行输入、输出清单参数以及相应生命周期环境影响潜值的统计计算与分析。以水资源和燃煤发电为基础的水源空调运行使用阶段的环境影响明显突出。水源中央空调环境影响的生命周期评价可为该产品环境绩效的改进设计提供有效的信息支持     

军用S-4烟幕酸雾污染的清除

提出了环保型军事训练的概念，针对大量使用的S-4烟幕的严重污染，构建了基于引射技术利用碳酸钠细粉和直接通过三通阀利用氨水的2种清除方法。通过实验确定，碳酸钠的最佳粒径为150目过筛，不同浓度氨水均有好的清除效果，碳酸钠、氨的最佳用量分别为S-4发烟剂的1．35和0.433倍。     

微生物与重金属的相互作用机理研究进展

微生物在自然界内种类繁多,并在重金属元素的生物地球化学循环中扮演着重要的角色。近年来,细菌与真菌对重金属的富集、转化作用成为此领域内的研究焦点。研究结果表明,细菌对重金属的富集、转化作用主要是通过胞壁吸附、氧化还原、细菌淋滤及与其它生物协同作用而进行的;真菌则主要是通过表面吸附与重金属硫蛋白的络合作用来富集环境中的重金属。文章对这些研究进展进行了综述,同时还介绍了菌根真菌在重金属的植物修复中所起的重要作用。     

大学校园的生态足迹探究

生态足迹分析法是评价绿色校园建设水平较好的指标之一,能定量揭示学校的生态状况,本文结合黑龙江科技学院的校园状况,简要介绍生态足迹成分法的原理和计算分析方法.研究结果表明,黑龙江科技学院2005年总生态足迹为18410.53 hm2,即需要18410.53 hm2生态生产性土地来支持学校的各类消费以及吸纳废弃物;人均生态足迹为0.94 hm2/人,与全国人均生态足迹1.5 hm2相比较,学校的生态状况比较乐观.